Prof. Fuping Huang

Guangxi Normal University, China

Title:

To study the assembly behavior from the modification of discrete {Co14} coordinate cluster base precursors

Abstract:

Using the modification of discrete {Co14} cluster-base complexes with potential active sites as precursors, a series of sophisticated cluster-base aggregate compounds with atom-precise structures, such as {Co14} cluster base MOLs, {Co11Cd6} cluster base MOFs, and giant clusters of {Co24}, {Co19}/{Co13Cd6} and {Co12}/{Co12Cd12} had been constructed, when induced by exogenous conditions. The conversion process, solution behavior and the differential structure-activity relationship were studied by solid-liquid combinated method.